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GHK-Cu is a photolabile copper(II) complex, and freeze-thaw cycling can disrupt the copper coordination sphere independently of any degradation of the peptide backbone, which means cumulative in-use exposure is a real variable and not a generic caution

Importantly, these metabolic effects enhance IFN- secretion and T cell effector functions, demonstrating that RES-mediated metabolic reprogramming can strengthen antitumor immunity (130, 131)

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Indeed, multidrug and radiation resistance in tumor cells have been associated with higher intracellular levels of GSH, and increased level of GSH is a poor prognostic factor in many types of cancer (31)