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As we age the cellular NAD + levels decline in part due to the reduced expression of one of the enzymes of NAD + salvage, nicotinamide phosphoribosyl transferase (NAMPT) as well as due to increased NAD + degradation via increased activity of the NAD + and NADP + hydrolyzing enzyme, CD38

Cleavage of the methyl ester presented a problematic step, inducing racemization and resulting in an ee of only 86%

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This hypothesis seemed reasonable, as S 0 species have previously been observed to be upregulated under oxidative stress conditions 26 and to exert cytoprotective effects 16,27