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The specific mechanism by which enzymatic reactions cause lipid peroxidation is that Acyl-CoA synthetase long-chain family member 4 (ACSL4) and Lysophosphatidylcholine acyltransferase-3 (LPCAT3) first activate polyunsaturated fatty acids (PUFAs) to bind to lipids in the cell membrane (e.g., phosphatidylethanolamine PE), forming the PUFA-PE complex (Su et al., 2019)

Another casualty of free radicals, our eyes are especially vulnerable to oxidative stress as theyre exposed to light, oxygen and irritants in the air, and antioxidants work to help neutralise these threats

2011 Sep;17(9):827-33.

As a purely cosmetic issue, there are several reasons why this occurs naturally