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In the H 2 O 2 -independent pathway, GPX3 modulates epigenetic responses by repressing S-glutathionylation of a signal transducer linked to histone modification (Jasmine and Joyous, 2022)

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Reduced electrophilicity, however, does not necessarily translate into proportionally reduced chemoproteomic labelling, as local cysteine microenvironments and experimental conditions can substantially modulate apparent proteome-wide engagement, thereby explaining the observed differences in labelling promiscuity across the chemoproteomic probes in the set