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Milk thistle (Silybum marianum) is a flowering herb related to the daisy and ragweed family

The N-terminal glycine amino group donates one nitrogen ligand to the copper, the imidazole nitrogen of the histidine side chain donates a second nitrogen ligand, and the deprotonated amide nitrogen of the Gly-His peptide bond donates a third nitrogen ligand

1 Introduction The purpose of this review is to assess the effects of atrazine and its chloro-metabolites DEA, DIA, and DACT (Figure 1) on the hypothalamic-pituitary-gonadal (HPG) axis in males to determine if plausible biological mechanisms could lead to cancer in humans at exposure levels found in food, water, or the workplace

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