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Studies of Glutathione show that a healthy cell should have over 100 times more reduced glutathione than its oxidized form

Apaf-1 is an evolutionarily conserved DNA sensor that switches the cell fate between apoptosis and inflammation

However, if you are looking to cut to the chase and cut out the processes your body requires to convert the NAC to glutathione, then glutathione wins the NAC vs glutathione choice

CrossRef Basic Research The Link between Mitochondrial Dysfunction and Sarcopenia: An Update Focusing on the Role of Pyruvate Dehydrogenase Kinase 4 Min-Ji Kim, Ibotombi Singh Sinam, Zerwa Siddique, Jae-Han Jeon, In-Kyu Lee Diabetes Metab J