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Unlike the nasopharyngeal microbiota, which remained relatively stable, the oropharyngeal microbiome exhibited marked smoking-related alterations, reflecting its higher sensitivity to CS exposure [52]

The health impact of smokeless tobacco products: a systematic review

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Since nicotine is a weak base (pKa=8.0), at a higher pH, a larger portion of nicotine is unprotonated (free-base) and nicotine is more volatile.62 Because of higher pH, a significant proportion of nicotine is present in the gas phase of inhaled aerosol