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[10] Diacetyl is produced during fermentation as a byproduct of valine synthesis, when yeast produces -acetolactate, which escapes the cell and is spontaneously decarboxylated into diacetyl

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The first campaign broke in New York, Chicago, and Los Angeles dailies but has been greatly enlarged to include every type of advertising vehicle. According to Stanley, the Marlboro Man came about this way: Leo Burnet saw a picture of a rugged, masculine-looking cowboy and felt such a type would prove to be a new concept for the presentation of cigarette

This collection of television commercials shows how the company framed the product as "tailored for the feminine hand," and, more to the point, as a symbol of women's empowerment