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Nicotine impersonates the neurotransmitter acetylcholine (ACh), and by binding to receptors ACh would usually bind to, stimulates the production of dopamine, which is involved in your bodys reward pathways

Quantitation of pyridyloxobutyl-DNA adducts in tissues of rats treated chronically with ( R )- or ( S )- N -nitrosonornicotine (NNN) in a carcinogenicity study